Pt纳米簇催化剂上丙烷脱氢反应研究.pdfVIP

Pt 纳米簇催化剂上丙烷脱氢反应的研究 刘博贤 侯凯湖∗ 河北工业大学化工学院，天津 300130 摘要: 结合溶胶凝胶法和化学还原法制备了负载型Pt 纳米簇丙烷脱氢催化剂。基于催化剂 的活性评价和BET 、XRD 、吡啶吸附红外光谱、TG 等表征结果考察了载体干燥时间、制备 方法、助剂Sn 等对Pt 纳米簇催化剂催化性能的影响。结果表明，采用SiO2 湿凝胶为载体， 当PVP 与Pt 质量比30，浸渍时间8h，负载型Pt/SiO2 催化剂表现出较好的催化性能；Sn 助 剂的添加对 Pt/SiO2 催化剂的反应性能影响显著，适量 Sn 的添加不仅增加了催化剂中的 Brönsted 酸中心和Lewis 酸中心，而且抑制了催化剂的积炭，明显改善了催化剂的稳定性和 催化活性。反应30h 后Sn/Pt 25 催化剂的 丙烷脱氢丙烯转化率和选择性和收率仍分别达到 18.8%和93% 。 关键词：溶胶凝胶； Pt 纳米簇； Sn 助剂； 稳定性 Propane Dehydrogenation over Pt Nanocluster Catalysts LIU Boxian* HOU Kaihu School of Chemical Engineering, Hebei University Of Technology , Tianjin 300130 Abstract: Supported Pt nanocluster catalysts for propane dehydrogenation were prepared by combining sol-gel method and chemical reduction method. Based on the performance evaluation and BET, XRD, pyridine IR absorption spectrum, thermogravimetry characterizations of the catalysts, effects of the support dry time, the preparation method, the promoter Sn added were investigated. The results indicated that the catalysts exhibited high catalytic activity, used silica sol-gel as support and under the conditions of PVP/Pt ratio 30 (mass), impregnation time 8h. The addition of Sn had significant influence on catalytic activity of the catalysts. A suitable concentration of Sn added not only increased the Brönsted acid sites and moderate/strong Lewis acid sites, but also prevented the catalyst from coking and improved significantly the catalyst ∗联系人：刘博贤，女 硕士 25 岁 Email:liuboxian_6577@yahoo.cn 联系电话：022 通讯地址：天津市红桥区光荣道8 号河北工业大学东院467 信箱 邮编300130 1 stability and activity. Propane conversion and propane selectivity were stil