K%2b%2fCl-%2cBr-+-H2O三元体系298K%2c313K%2c333K时相平衡研究的论文.pdfVIP

+ - - K /Cl ,Br -H O 三元体系298K，313K，333K 时相 2 平衡研究1 翁延博，王彦飞，王静康，尹秋响 (天津大学化工学院，天津 300072) + - - 摘 要：用等温溶解平衡法研究了三元体系K /Cl ,Br -H O 在298K 、313K、333K 下的相平衡关系，测定了饱 2 和溶液的密度、折光率等物化性质。该三元体系在三个温度下的溶解度等温图有 1 个固相区－K(Cl,Br)及 1 条 单变量曲线，该体系属于固体溶液型。用Pitzer 模型检验了测得的三元体系在298K 、313K、333K 下的溶解度， 并用经验公式对平衡液相的密度、折光率进行了计算，计算值与实验值基本吻合。 关键词：水盐体系；氯化钾；溴化钾；相平衡；固溶体；Pitzer 模型 A Study On The Phase Diagram For The Ternary System + - - K /Cl ,Br -H O At 298K, 313K And 333K 2 WENG Yan-bo , WANG Jing-kang, YIN Qiu-xiang , WANG Yan-fei (School of Chemical Engineering and Technology Tianjin University, Tianjin 300072, PRC) + - - Abstract: Solubilities of the ternary system K /Cl , Br -H O were investigated at 298K, 2 313K, 333K by isothermal method. Physico-chemical properties of solutions, such as density, refractive index, were determined. The phase diagram of the system includes one univariant curve and one crystallization field: K(Cl,Br). The ternary system is a solid solution. Pitzer model of electrolyte solution was used to check the obtained solubilities. The empirical equations of density and refractive index related to its composition were used to correlate the data. The calculated values are in agreement with the experiment values on the whole. Keywords:salt-water system; potassium chloride; potassium bromide; phase equilibrium; solid solution; Pitzer model 作者简介：翁延博，1981 年，博士研究生。Email ：mortaryoyo@ 我国钾肥资源短缺，主要靠大量进口满足市场需求。在资源全球化时代，实施“走出去”战 略，充分利用“两种资源”、“两