采用非平衡级模型模拟催化精馏过程的研究 精品.pdfVIP

1128 PETROCHEM ICAL TECHNOLOGY 2007 36 11 1, 2 1 1 1 1 1 王 峰 , 赵 宁, 李军平 , 肖福魁, 魏 伟 , 孙予罕 ( 1. , 030001; 2. , 100039) [] , , , ( DMC ), , DM C 3. 78% , , [] ; ; ; ; [] 1000- 8144 ( 2007) 11- 1128- 06 [] TQ 028 [] A Sim ulation of Catalytic D istillation Process U singNon- Equilibrium StageM odel 1, 2 1 1 1 1 1 W a g Fe g , Zhao N i g , Li Ju pi g , X iao Fuku i , W eiW ei , Su Yuha ( 1. State Key Labo rato ry o f CoalCo versio , I stitute o f CoalChem istry, Chi ese A cadem y o f Scie ces, Taiyua Sha x i030001, Chi a; 2. G raduate School o f Chi ese A cadem y of Scie ces, Beiji g 100039, Chi a) [ Abstract] The reactio s i distillatio co lum w ere classified i to ge eratio reactio s a d co sum ptio reactio s. A mi proved trid iago al m atrix m ethod w as developed by defi itio of co sum ptio reactio rate co sta t. The catalytic distillatio process for sy thesis of dmi ethyl carbo ate ( DM C) by urea m etha olysis over solid catalyst w as smi ulated by the established o - equilibrium stage m ode,l a d the mi proved trid iago al m atrix m ethod w as used to solve the m odel equatio s. Com pariso of smi ulated resu ltsw ith expermi e t data show s that mea relative error of DM C yield is 3. 78% u der d iffere t co d itio s such as differe t total pressures a d reactio tem peratures. The mi proved tridiago almatrix m ethod could avoid the egative values of the liqu id compositio s duri g the calculatio s, a d restrai the fluctuatio of compositio s by slow i g dow the variatio s of the values i the iteratio . The smi ulated res