精品范文MIL-101不饱和金属位氨基改性-SI.pdfVIP

Supporting Information © Wiley-VCH 2008 69451 Weinheim, Germany Supporting Information Amine-grafting on Coordinatively Unsaturated Metal Centers of MOFs: Catalytic and Metal Incorporation Consequences 1 1 1* 2 Young Kyu Hwang , Do-Young Hong , Jong-San Chang , Sung Hwa Jhung , You- 1 3 4 4 5 Kyong Seo , Jinheung Kim , Alexandre Vimont , Marco Daturi , Christian Serre , and Gérard Férey5* 1 Catalysis Center for Molecular Engineering, Korea Research Institute of Chemical Technology (KRICT), P.O. Box 107, Yusung, Taejon 305-600 (Korea) Fax: (+82)-42-860-7676, E-mail: jschang@krict.re.kr 2 Department of Chemistry, Kyungpook National University, Daegu 702-701 (Korea) 3 Department of Chemistry, Division of Nano Sciences, Ewha Womans University, Seoul 120-750 (Korea) 4 Laboratoire Catalyse et Spectrochimie, UMR 6505, CNRS/ENSICAEN et Université de Caen Basse-Normandie, 6, boulevard Maréchal Juin, 14050 Caen Cedex (France) 5 Institut Lavoisier, UMR 8180, Université de Versailles Saint Quentin, 45 avenue des Etats- Unis, 78035 Versailles Cedex (France), E-mail: ferey@chimie.uvsq.fr Experimental Section 1. Synthesis of MIL-101 MIL-101 was initially prepared from hydrothermal reaction of terephthalic acid (166 mg at 1 mmol) with Cr(NO ) .9H O (400 mg at 1 mmol), HF (0.2 ml at 1 mmol), and H O (4.8 ml 3 3 2 2 at 265 mmol) at 493 K for 8 h. This reaction produced a highly crystallized green powder of