合成四甲氧甲基甘脲最佳工艺的研究.pdfVIP

! 20! SHANDONG CH EM ICAL IN DU STRY 20 10 39 李文杰, 刘爱花, 薛永强 ( , 030024) : , ; ; , : , , : 1: 16, 3h, 40 : ; ; ; : TQ 6 12. 6; O 62 1. 3 : A : 1008- 02 1X ( 20 10) 11- 0020- 03 S tudy on O ptim um Syn th esis C ond itions of Tetram ethoxym ethy l G lycoluril L I Wen - j ie , L IU A i- hua, X UE Yong - q iang ( Departm ent o f A pp ied Chem istry, T a iyuan Un iversity of T echno ogy, T a iyuan 030024, Ch ina) Abs tract: G yco uri w as synthesized first y u sing carbam ide and biform y as raw m ater ia in acidic conditions, and then tetram rth o g yco uri w as obta ined by the reaction of the g yco uri w ith form a dehyde in the a ka escence cond itions. F ina y, from the ob tained tetram rth o g yco uri, the end product tetram ethoxym ethy g yco uri w as prepared by acid- cata yzed reaction w ith carb ino. A t the sam e t mi e, the opt mi um synthesis cond itions o f the end product w as invest igated, and the in f uences of the reaction cond itions on its yie d, such as proportion of raw m ateria s, reaction tem perature, and reaction t mi e w ere d isscu ssed. T he resu ts show ed that the m ost co rre a ted factors w ith the y ie d of the tetram e thoxym ethy g yco uri w ere the ro e o f proport ion o f raw m ateria s, reaction tem perature, and reaction tmi e. T he optmi um synthesis conditions w ere as fo ow s: the m o ar ratio of tetram ethoxym ethy g yco uri to carb ino w as 1: 16, react ion t mi e 3h and react ion temperature 40 . K ey w ord s: g yco uri; tetram rth o g yco uri; tetram ethoxym ethy g yco uri; optmi um cond ition 2, 4, 6, 8 - [ 3, 3, 0] -