染料敏化太阳能电池用过渡金属化合物对电极的研究进展.pdfVIP

第28 卷 第9 期 无 机 材 料 学 报 Vol. 28 No. 9 2013 年9 月 Journal of Inorganic Materials Sep. , 2013 文章编号: 1000-324X(2013)09-0907-09 DOI: 10.3724/SP.J.1077.2013.12780 染料敏化太阳能电池用过渡金属化合物对电极的研究进展 王桂强, 王德龙, 况 帅, 禚淑萍 ( 山东理工大学 化工学院, 淄博 255049) 摘 要: 由于成本低、制作工艺简单、光电转换效率高, 染料敏化太阳能电池被认为是传统太阳能电池最有力的 竞争者之一。染料敏化太阳能电池常用的对电极是Pt 电极, Pt 价格高, 储量少, 因此寻找一种价格便宜且催化性 能较好的材料代替Pt 制备对电极是目前的研究热点。过渡金属化合物品种多、制备过程简单、价格低且催化性 能好, 近年来受到人们的广泛关注, 是代替 Pt 制备染料敏化太阳能电池对电极最好的材料之一。本文综述了染 料敏化太阳能电池过渡金属化合物对电极的研究现状, 对过渡金属化合物对电极的性能特点及今后研究的重点 进行了分析。 关 键 词: 对电极; 过渡金属化合物; 染料敏化太阳能电池; 综述 中图分类号: TK513 文献标识码: A Research Progress on Transition Metal Compound Used as Highly Efficient Counter Electrode of Dye-sensitized Solar Cells WANG Gui-Qiang, WANG De-Long, KUANG Shuai, ZHUO Shu-Ping (College of Chemical Engineering, Shandong University of Technology, Zibo 255049, China) Abstract: Dye-sensitized solar cells (DSC) has been considered as one of the most promising alternatives to conven- tional photovoltaic device due to its low cost, simple fabrication process and high conversion efficiency. Pt-loaded con- ducting substrate has been widely exploited as the standard counter electrode for DSC. However, Pt is expensive and rare, so it is most desirable to seek a low-cost substitute for Pt in counter electrode of DSC. Transition metal compound has been demonstrated to be one of the most promising counter electrode materials for DSCs owing to its low cost, simple fabrication, broad variety of materials and good catalyt