废木材在粉粒流化床中低温催化分解制氢地研究.pdfVIP

G032 废木材在粉粒流化床中低温催化分解制氢的研究 王昶 李崇武 贾青竹 天津科技大学 材料科学与化学工程学院（３００２２２） 要 以废木材为制氢原料，使用粉粒流化床反应器，分别调查热分解过程中二种催化活性不同流化介质，热 分解温度以及三种木材对产物分布和收率的影响。废木材在惰性介质SiO 流化介质中，热分解产物中的无机化合 2 物、低分子碳氢化合物以及轻质芳烃化合物都随着热分解温度的增加而增加。1173K 时，初期分解来的焦油几乎 都转化为低分子化合物，其中氢气的收率为原料氢重量的23%，但在NiMo-A 催化剂情况下，863K 时，几乎为无机 产物，其中氢气的收率达原料氢重量的60%，而且在更低温度723K 下，氢气的收率仍可达到58%。在相同的热分 解条件下，木材的种类对产物分布和收率的影响很小。 关键词 氢能 生物质 催化热解 流化床 中图分类号 TQ351.2 文献标识码 A 文章编号 RESEARCH ON PRODUCTION OF HYDROGEN FROM WASTE WOOD BY CATALYTIC PYROLYSIS AT LOW TEMPERATURE WANG Chang LI Chongwu JIA Qingzhu (College of Material Science Chemical Engineering, Tianji n University of Science Technology) Abstract In a process of catalytic pyrolysis of waste wood as a material for production of hydrogen effects of two kinds of catalysts, pyrolysis temperature and three kinds of waste woods upon distribution and yield of pyrolysis production were investigated using a powder particle fluidized bed. In the case of SiO2 as a fluidizing medium in the bed, the yields of inorganic gases, hydrocarbon gases and light aromatic hydrocarbons of products increased with increasing pyrolysis temperature and the yield of hydrogen based on the weight of hydrogen in the wood was only 23% even at 1173K of high temperature. In the case of NiMo-A, the pyrolysis products were almost inorganic gases and the hydrogen yield reached about 60% at 863K and 58% even at 723K. The effect of the wood kind on the distribution and yield of the products were very small at the same operating conditions. Keywords hydrogen energy, biomass, catalytic pyrolysis, fluidized bed [2] 言 的能源，与水相比更具有开发和利用的价值 。因