LbL层层纳米自组装法制备新型微胶囊.pdfVIP

16 4 化 学 进 展 Vol. 16 No.4 2004 7 PROGRESS IN CHEMISTRY July, 2004 LbL 层层纳米自组装法制备新型微胶囊* 梁振鹏 王朝阳 孙启龙 童 真* * ( 华南理工大学材料科学研究所 广州510640) 本文介绍了 一 新颖灵活的制备纳米或微米胶囊方法 层层纳米自组装法( b ) b 法 制备微胶囊的显著优越性在于能够在纳米尺度上对胶囊的大小组成结构形态和囊壁厚度进行精确的控 制这 新型的微胶囊在生化制药药物控释化妆品和催化等领域具有潜在的应用前景 层层自组装 聚电解质多层膜 微胶囊 微反应器 :TB383; O6473 : A : 1005281X(2004) Novel Microcapsule Fabricated by LbL Nano SelfAssembly * * L iang Zhenp eng Wang Chaoyang Sun Qilong Tong Zhen (Research Institute of Materials Science, South China University of Technology, Guangzhou 510640, China) Abstract The article focuses on a novel and versatile technique of layerbylayer deposition( b ) , developed for preparing nanoor microcapsules. The strategy outlined readily affords precise control over the size, composition, con struction, shape and wall thickness of the hollow capsules. Consequently these capsules have potential applications in biochemistry, pharmacy, controlledrelease, cosmetic and catalyst. Key words b selfassembly; polyelectrolyte multilayer; microcapsule; microreactor SiO ( PDAD 2 MA C) [8, 10 13] TiO 2 Iler 1966 PDADMAC[ 13, 14] Fe O 3 4 (layer by layer, b ) ( PAH) [ 15 17] ( lipid) [ 1] [18] [ 19] 3+ [ 20] 1990 , Decher (PSS) P