含芴基铕配合物LED.pdfVIP

Appl Phys B DOI 10.1007/s00340-009-3638-1 A europium(III) organic ternary complex applied in fabrication of near UV-based white light-emitting diodes H. Wang · P. He · S. Liu · J. Shi · M. Gong Received: 8 January 2009 / Revised version: 21 May 2009 © Springer-Verlag 2009 Abstract A β-diketone, 2-acetylfluorene-4,4,4-trifluoro- (x = 0.66, y = 0.33). A white LED with CIE chromatic- butane-1,3-dione (HAFTFBD), and its three europium(III) ity coordinates (x = 0.32, y = 0.32) was prepared with complexes, Eu(AFTFBD) ·2H O, Eu(AFTFBD) (TPPO) Eu(AFTFBD) phen as red phosphor, indicating that 3 2 3 2 3 and Eu(AFTFBD) phen, were designed and synthesized, Eu(AFTFBD) phen can be applied as a red component for 3 3 where TPPO was triphenylphosphine oxide and phen was fabrication of near ultraviolet-based white light-emitting 1,10-phenanthroline. The complexes were characterized diodes. by IR, UV-visible, photoluminescence (PL) spectroscopy and thermogravimetric analysis (TGA). The results show PACS 42.70.-a · 05.65.+b · 32.50.+d · 61.43.-j that the Eu(III) complexes exhibit a high thermal stabil- ity,and wide and strong excitation bands when monitored at 613 nm. Excited by ∼395 nm near UV light, the com- 1 Introduction plexes emitted strong and characteristic red light due to f –f transitions of the central Eu3+ ion, and no emission from It is known that white light-emitting diodes (LEDs) can the ligands was found. The photoluminescence mechanism offer