氧化铝毛细管微滤膜的制备与表征.pdfVIP

J35 氧化铝毛细管微滤膜的制备及表征 6 朱瑾 范益群 徐南平 (南京工业大学化学化工学院，材料化学工程国家重点实验室，江苏 南京 210009) 摘要：陶瓷毛细管膜具有装填面积大，液体渗透阻力小的优点，在液体分离领域有很好的应用前景。与单管支撑 体相比，毛细管支撑体具有尺寸小、壁厚薄的特点，虽然对于单管支撑体上的成膜过程研究较多，但目前针对毛 细管支撑体上的成膜过程研究报道不多。本文主要考察了制膜液性质和膜制备工艺条件对氧化铝毛细管微滤膜制 备的影响，并与单管膜的制备进行了比较。结果表明，在毛细管与单管上的成膜规律差别较大，薄膜形成在毛细 管上的成膜过程中起到了重要作用，毛细管膜的液体渗透通量普遍比单管膜高。 关键词：毛细管膜；毛细过滤；薄膜形成；陶瓷 Preparation and characterization of Al O capillary 2 3 microfiltration membranes ZHU Jin ，FAN Yiqun ，XU Nanping (Department of Chemistry and Chemical Engineering，State Key Laboratory of Material-Oriented Chemical Engineering, Nanjing University of Chemical Engineering, Nanjing, Jiangsu, 210009) Abstract: Ceramic capillary membranes have large packing densities, excellent permeance performances and good prospects of wide application in liquid separation. Compared with tubular support, capillary support has a smaller outer diameter and thickness. Few literatures reported the process of membrane formation of capillary membranes although extensive studies have been carried out on tubular membranes. This paper mainly studied the effects of suspension property and preparation parameters on the process of membrane formation of Al O capillary microfiltration membranes. It is 2 3 demonstrated that film-coating effects have played an important role in the process of membrane formation for capillary membranes and the permeance of pure water for capillary membranes are always higher than that for tubular membranes. Key words: capillary membrane, capill