本科毕业论文-模拟239Pu放射性废物的钆锆烧绿石.docVIP

模拟239Pu放射性废物的钆锆烧绿石 固化及热学性能研究 摘要：本研究利用Ce4+作为Pu4+的模拟替代物质，利用高温固相反应法开展固化体的制备，在对所制备固化体的物相及微观形貌等进行表征的基础上，对固化体的热稳定性（室温热导率、、热扩散系数）进行研究其研究成果将为今后锕系或次锕系核素人造岩石固化提供较为真实的科学数据。 关键词：239Pu；放射性废物；钆锆烧绿石；固化；热学性能  Reasearch of plutonium and thermal properties for Gd2Zr2O7 pyrochlore Abstract: The research used Ce4+ as the alternative material of 239Pu, and manufactured the solidified body by high temperature solid phase method, based on the phase and microstructure of the cured body prepared were characterized, this research studies on the thermal stability of the cured body (thermal conductivity, specific heat and thermal diffusivity at room temperature). The results showed that the superlattice peaks of Pyrochlore disappear , when the solution of Ce4+ in cured body is more than 10mol%, and the cured body changed from pyrochlore phase into fluorite phase.When the solution of Ce4+ is 10mol%，the morphology of the sample can be seen irregular and plate-like from the SEM images.This research uses Thermal conductivity detector with the Hot Disk method to measure the pyrochlore’s thermal conductivity, specific heat and thermal diffusivity, from this article it can be seen that the pyrochlore’s thermal conductivity, specific heat and thermal diffusivity is inscreased with the inscreasing of the solution of Ce4+. The research results will actinide or minor actinide synroc provide more real scientific data in the future. Key words: 239Pu, radioactive waste, gadolinium zirconate pyrochlore, solidification, thermal properties  目 录 1 绪论 1 1.1 选题背景 1 1.2 高放废物的处理和处置 1 1.2.1 玻璃固化 2 1.2.2 水泥固化 4 1.2.3 人造岩石固化 6 1.3 国内外研究状况 9 2 实验 11 2.1 钆锆烧绿石固化体制备 11 2.1.1 化学试剂和实验仪器 11 2.1.2 固化体制备 11 2.2 样品的表征方法 14 2.2.1 XRD衍射分析 14 2.2.2 SEM分析 15 2.3 热学性能分析 16 2.3.1 实验仪器与方法 16 2.3.2 样品热学系数的测试 18 3 结果与讨论 20 3.1 样品表征 20 3.1.1 XRD分析 20 3.1.2 SEM分析 23 3.2 热学性能分析 27 3.2.1 热扩散系数 27 3.2.2 热导率 28 3.2.3 比热 29 4 结论 31 致谢 32 参考文献 33  1 绪论 1.1 选题背景 能源短缺已成为当今社会所面临的一个极具挑战性的问题，为开发新能源，核能成为有一个较好的选择核能在造福人类的同时也给社会带来了严重的问题—