几种难生化芳香化合物的电催化降解研究_结构对降解活性的影响.pdfVIP

37 1 浙　江　大　学　学　报( ) Vol. 37 o. 1 2003 1 Journal of Zhejiang University( Engineering Science) Jan. 2003 ——结构对降解活性的影响 周明华, 吴祖成, 汪大 ( , 310027) : . , 3 , 40%, 16%43%. h COD COD . : . , : ; . Hammett . . : ; ; ; ; : T Q150. 9;X783:A: 1008-973X( 2003)01-0074-04 Study on electrocatalytic degradation of biorefractory aromatic compounds Effect of structure on degradation reactivity: ZHOU Ming-hua, WU Zu-cheng, Wang Da-hui (I nstit ute of E nv ir onmental E ng ineer ing , Zhej iang Univ er sity , H angz hou 310027, Ch ina) Abstract: This study on the electrocatalytic degradation of four typical aromatic compounds, aniline, , - - , 3 chlorobenzene p chlorophenol and p nitrophenol showed that within h the aromatic compounds could be completely removed; and that the COD removal rate could be more than 40% . During degradation, the electrochemical oxidation index (E OI ) were in range from 16% to 43%. T he removal of aromatic com- - ; pounds and COD were found to follow well an apparent first order kinetic reaction and were in the order - - . aniline chlorobenzene p chlorophenol p nitrophenol T he ring substituents influenced the electrocat- alytic reactivity of the aromatic compounds significantly in sequence: group of H2 , Cl and O2. T he ad- dition of the hydroxyl group on the benzene ring would lead to the decrease of electrocatalytic reactivity. The relationship between structure and electrocatalytic reactivity was interrupted by Ha