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审稿专家意见:.doc
审稿专家意见:
1. 引言中,对文献的总结,应该集中在磷石膏活化的现有研究成果,介绍国内外已经达到的水平。2. 选用的晶种应该公开其化学成分,并且与现有国内外研究成果进行比较。3. 在3.1节提出的反应方程式(1)和(2),是否引自文献。如果是自己提出,应该有其它证据。4. 其它意见请见原文批注。Hydration of Activated Anhydrate Phosphogypsum
YANG Min, QIAN Jueshi 2
(1 College of Chemistry and Chemical Engineering, Guizhou University, Guiyang 550003, China
2 College of Materials Science and Engineering, Chongqing University, Chongqing 400045, China)Abstract: Phosphogypsum(PG) calcined at 500℃ was activated by K2SO4 and salt lime with loose structure as seed crystal. To determine the effect of activation, hydration of the anhydrate PG activated was investigated by examination of the setting time, the proportion of hydrated anhydrate PG, the microstructure of the hardenite and the resistance to water. Results suggest that activated anhydrate PG hydrates much more rapidly than that without activators. The activated anhydrate PG has proper setting time and hydrated proportion. The resistance to water was greatly improved. SEM photos show that the set activated PG has hydrated products of rod-like and closely connected crystals. The different addition of activator leads to different compact structure.
Keywords: hydration; anhydrate phosphogypsum ; activation; K2SO4 ; seed crystal
1 Introduction
Anhydrate gypsum hydrates slowly, which affects its utilization greatly[1,2]. Activator is usually used to accelerate the hydration of anhydrate gypsum[3,4]. The most widely used chemical activators are sulfates and alkalies[5,6]. However, the effect of single activation isn’t desirable and combined activation is required.
In our work, salt lime with loose structure was produced by controlling sintering temperature to be used as the seed crystal to induce the formation and development of crystal nucleus of dihydrate gypsum during the solution of anhydrate gypsum. K2SO4 was added to act as sulfate activator. Considering the extensive way with low cost and easily pretreated of PG is important, PG is selected to prepar
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