木质素基吸附材料的制备及其吸附性能研究_朱媛媛.pdfVIP

第32 卷 第1 期 Vol. 32 No.1 第 第期11 期 2009 年1 月 Environmental Science Technology Jan. 2009 木质素基吸附材料的制备及其吸附性能研究 1 2* 1 朱媛媛 ，蒋新元 ，胡迅 （1.中南林业科技大学资源与环境学院； 2. 中南林业科技大学材料科学与工程学院，湖南 长沙 410004） 摘 要：以木质素磺酸盐为原料，利用反相悬浮聚合技术，成功制备木质素基吸附材料，并研究了交联剂用量、分散剂用量、聚合温度、聚 合时间及体系酸度等对悬浮聚合反应及其阳离子染料亚甲基蓝吸附性能的影响。实验结果表明，所制备的吸附材料对亚甲基蓝有较快的吸 附速度和较高的吸附量，当木质素吸附材料对亚甲基蓝的吸附量达到17.71mg/g 后，吸附趋向饱和，温度保持在30℃左右有较高的吸附量。 关键词：木质素；吸附材料；阳离子染料；亚甲基蓝；吸附 中图分类号：X132 文献标志码：A 文章编号：1003-6504(2009)01-0071-04 Preparation of Lignin-based Adsorption Material and Its Adsorption Properties 1 2* 1 ZHU Yuan-yuan ， JIANG Xin-yuan ， HU Xun （1.School of Resource and Environment ；2.School of Material Science and Engineering ，Central South University of Forestry and Technology ，Changsha 410004 ，China） Abstract ：A lignin-based adsorption material was successfully prepared with sodium lignosulfonate as raw material by reversed phase suspension polymerization technique. Effect of cross -linking agent dosage ，dispersing agent dosage ，polymerization temperature ，polymerization time and acidity on suspension polymerization and adsorption properties for methylene blue as cationic dye were studied. Experimental results indicated that the prepared adsorption material had quicker adsorption speed and higher adsorptive capacity to methylene blue. After adsorptive capacity for lignin-based adsorption material to methylene blue achieved 17.71mg/g，adsorption tended to saturation. About 30℃ was bene