废悬浮床催化剂中钼的回收应用研究.pdfVIP

Hans Journal of Chemical Engineering and Technology 化学工程与技术, 2012, 2, 117-121 doi:10.4236/hjcet.2012.24021 Published Online October 2012 (/journal/hjcet.html) Recovery and Application of Molybdenum from Waste Suspension Bed Catalyst 1 2 2 2 1 1 1 Liwen Luo , Fugang Li , Qian Hao , Wen’an Deng , Zhen Chang , Peng Guo , Aixia Zhang 1College of Science, University of Petroleum China, Qingdao 2College of Chemical Engineering, University of Petroleum China, Qingdao Email: luolw@ Received: Aug. 20th th th , 2012; revised: Sep. 16 , 2012; accepted: Sep. 26 , 2012 Abstract: The main content of this study is the recycling of molybdenum in hydrogenation spent catalyst of suspension bed. This project use the method of uniform experiment design and the processing route is as follows: calcinations- leaching-purification-subsiding molybdenum, the purpose is to require the maximum recycle of molybdenum in the spent catalyst and the corresponding experiment condition. The results show that the maximum extraction rate of Mo is 99.49%. The conditions are that in the phase of calcination temperature is 600˚C, time is 2 h, the molar multiple of Na CO is 2.5, the temperature of leaching is 95˚C, time is 2.5 h, the liquid-solid ratio of leaching is 4:1, in the phase of 2 3 subsiding molybdenum the precipitation rate of Mo is 91.33% due to the relatively low concentration of Mo in the leaching solution. Keywords: Molybdenum; Spent Catalyst; Suspension Bed; Calcination; Leaching 废悬浮床催化剂中钼的回收应用研究