水体系下羟化聚天冬氨酸合成工艺的研究.pdfVIP

June 2008 现代化工 28 6 ∀ 56 ∀ Modern Chemical Industry 2008 6 赵彦生, 宋鸿梅, 刘永梅, 郭 疆 ( 太原理工大学化学化工学院, 山西 太原030024) : ( PSI) 2- ( AE) , - ( HPAP) : 25 , 9 h, AE/ PSI 04, 18% HPAP : ; ; ; :TQ085 : A : 0253- 4320( 2008) 06- 0056- 02 Study on synthesis of poly(aspartic) acid derivatives with hydroxyl in water ZHA O Yansheng , SONG H ongmei, LI U Yong mei, G UO Jiang ( College o Chemistry and Chemical Engineering, T aiyuan University o Technology, Taiyuan 030024, China) Abstract: Poly( aspartic) acid ( PASP) derivatives w ith hydroxyl ( HPAP ) are synthesized by the nucleophilic addition reaction o polysuccinimide ( PSI) w ith ethanolamine( AE) in w ater. The e ects o reaction conditions on the scale inhibiting per ormance o Ca ( PO ) are studied by orthogonal experiments .The results show that the optimized conditions are as ollow s: 3 4 2 9 h o reaction time, 25 o reaction temperature, 04 o AE/ PSI molecular ratio, 18% o reactants mass raction .The HPAP has higher scaleinhibiting capability than that o PASP or Ca ( PO ) . 3 4 2 Key words: water medium ; poly( aspartic) acid derivatives w ith hydroxyl ; synthesis; scale inhibiting per ormance [ 1] , , , (PASP) , HPAP1 , PASP [ 2- 4] , PASP , , ( PSI) 2- , , [ 5] , (PSI) 2- , 图1 HPAP 的合成原理 ! ! ! ( HPAP) , 12 Ca2+ HCO- ( Ca