碳纳米管负载Cu-Co复合氧化物的富氢气氛中CO催化消除.pdfVIP

CHINESE J0URNAL 0F CHEM ICAL PHYSICS VOLUME27．NUMBER 5 0CT0BER 27，2014 ARTICLE Cu—CoCompositeOxidesSupportedonM ulti—walledCarbon Nanotubesfor CatalyticRemovalofCO inaH2一richStream NingLiu，Yu—xianGao，Wen—dongW ang ，Wei—xinHuang CASKeyLaboratoryofMaterialsForEnergyConversionandDepartmentofChemicalPhysics,University ofScienceandTechnologyofChina Hefei23002fi，China (Dated：ReceivedonMay16，2014；AcceptedonMay29，2014) Multi—walledcarbonnanotubesfMWCNT1supportedCu—Cocompositeoxidescatalystswere preparedbyanultrasonicationtreatment—aidedimpregnationmethod．Thestructureprop— ertiesofthecatalystswerecharacterizedbyXRD TEM ，H2一TPR，XPSandRamanspectra， indicatingthestronginteractionsbetweenCuandComixedoxidesaswellasbetweenmetal oxidesandMW CNT support．ThecatalyticperformanceofCO removalinaH2一richstream wasexamined．IncontrasttothesingleCuandCocatalyst．theuniqueperformancewasob— servedforCu—Cocompositecatalysts，whichfeaturesanunusualreactionpathwaythrough thecombination ofC0 preferentialoxidationandCO methanationespeciallyathighreac— tiontemperature．TheoptimalcatalystwithCu／Coratioof1／8canachievethecomplete CO conversioninawidertemperaturerangeof150-250。C underthespacevelocityashigh as 120L／(h．g1whichdemonstratesapromisingcatalystofrtheeffectiveCOremovalina H2-rich stream ． Keywords：Copper，Cobalt，Carbonnanotube，CO preferentialoxidation，COmethanation I．INTR0DUCT10N attracted muchattention becauseofthelow costand high selectivity． However．PROX reaction isdeacti— Thehydrogen productionisoneofthecrucialtech— vatedmainlyduetothecompetitiveH2oxidationand nologiesofrthefuturehydrogen energyeconomy and reduction ofmetaloxidesattemperaturehigherthan thepolymerelectrol