模拟生物采样装置应用.pptVIP

Study on SPMD application in sampling groundwater Fei LIU Dept. of Water ResourcesEnvironment China University of Geosciences(Beijing) feiliu@cugb.edu.cn Main Contents(chlorinated pesticides) 1 .Background 2. Analytical method 3. Simulated experiment conducted in lab 4. Field application Background 2001.5.23 POPs treaty signed in Stockholm includes China. POPs：pesticides ( aldrein,chlorodane,DDT,dieldrin,endrin,heptachlor,Dechlorane mirex,Toxaphene,HCB) Industrial chemicals(HCB,PCBs) Byproducts（PCDD,PCDF, HCB,PCBs） Impacts on Environment Atmosphere Waterbody soil Problems caused by pesticides Kill the beneficial birds and insects while kill the pests Accumulation in animal by food chain Make the pests have tolerance ability Pescides used in China pesticides Production DDT 1981－1999 30 tons。 Commonly detected in water body/sediment/corn/vegetable/fruit/meat/people tissue aldrin Not large quantity dieldrin Not large quantity endrin Not large quantity Chlorodane 1977－1978 3000 tons，it was banned in 1979. heptachlor 1967－1969 17 tons BHC 60s-80s 81595 tons Commonly used and detected Residue of BHC and DDT in food（10-3mg/kg） Foods Northeast Northern China Southwest Eastern China Southern China BHC DDT BHC DDT BHC DDT BHC DDT BHC DDT Crops 5.3 6.5 2 95 1.6 33 3.0 3.9 44 24 Vegetables 2.1 6.1 14 95 2.6 1.9 1.5 3.5 6.7 24 Fruits 2.1 12 14 95 0.99 0.9 1.5 3.5 9.1 46 Plant oil 100 65 21 95 9.2 16 15.0 19 12 27 Chicken 4 13 25 98 8.7 25 2.1 5.2 7.3 25 Aquatic food 6 33 20 97 4.1 35 2.3 2.3 7.6 25 Eggs 6.6 32 18 95 3.6 8.6 1.6 4.8 16 27 Milk 70 50 14 95 2 2.0 2.2 8.1 12 27 Why do we choose the SPMD? Lower concentration in groundwater Pesticides can be accumulated by aquatic life We care about the information not on a time point Structure and potential of SPMD Two layers of low density polythene. Triolein inside Caculation concentration of pollutant in SPMD 1 α-BHC,2 HCB,3 β-BHC,4 γ-BHC,5 δ-BHC,6 heptachlor、7 aldrin,8heptachlor epo