Ru_Schiff_base_Y复合材料对苯加氢反应的催化性能研究.pdfVIP

34 3 V o.l 34 No. 3 2006 6 Jo rnal of F el Chem istry and Techno logy J n. 2006 : 0253-2409( 2006) 03-0364-04 R ( Schiff-base) /Y 陈 萍, 宋明刚, 范彬彬, 马静红, 李瑞丰 ( , 030024) : R ( Sch iff-base), Y XRDN2 FT-IRDRSDTA , ( Sch iff-base) , , R /Y , : R ; ; ; ; Y : TQ032 : A Catalysis ofRu(Schiff-base)/Y composite catalysis for benzene hydrogenation CHEN Ping, SONG M ing-gang, FAN B in-b in, MA Jing-hong, L IR -i feng (Key Laboratory of C oal Science and Technology, MOE Instit te of Special Chem ica ls, Taiy an Un iversity of Technology, Taiy an 030024, China ) Abstract: R ( Sch iff-base) comp lex, a novel catalyst for benzene hydrogenation at low temperat re, w as en- caps lated in the s percages of zeoliteY by flexible ligandm ethod. The res lts of XRD, N -desorption, FT-IR, 2 DRS, DTA and catalytic reaction show that Sch iff-base ligands in the prepared composite catalyst changed the e- lectronic state of centralmetal atom, th smade the catalyst to form transition coordinative state w ith reaction s b- strate more easily and facilitating the prod ct form ation. Compared w ith R /Y prepared by ion-exchange meth- od, in p re benzene hydrogenation, the catalytic activ ity of R ( Sch iff-base) /Y increased sign ificantly. Smi lta- neo sly, the geometry size of different Sch iff-base ligands has strong infl ence on the catalytic perform ance of prepared com posite catalysts. Key ords: R com posite catalysts; Schiff-base; hydrogenation of benzene; complex activation; Y type zeo lite [ 3] [ 4] [ 5] , : A l O SiO