_萘乙醚的微波合成研究.pdfVIP

33 6 Vol. 33 No. 6 2004 12 Applied Chemical I ndus ry Dec. 2004 赵胜芳, 陈年友, 明键伟, 王菊平, 孙国建 ( , 438000) : , , , , 3. 6 g ( 0. 025 mol) , 30 mL, 7 mL , 260 W , 40 min , 71% , ( 6 h 40 min) , ( 60% 71%) :; ; ; : O 625 : A : 2004) 0600250 3 Study on the synthesis of naphthyl ethyl ether under microwave radiation ZH A O S hengf ang , CH EN N iany ou, MI N G J ianw ei , WA N G J up ing , S UN G uoj ian ( Depar men of Chemis ry, Huangg ang N ormal U niversi y , Huangg ang 4 38000, China) Abstract:T his paper s udies he syn hesis of naph hy l e hyl e her under microw ave radia ion w i h naph hol and anhy drous alcohol as raw m a erial and concen ra ed sulfuric acid as ca alys . I also ex plores he eff ec s of reac ion condi ion upon he yields. T he ex perimen al resul s show ha naph hol is 3. 6 g( 0 . 025 mol) , anhydrous alcohol is 30 mL, concen ra ed sulfuric acid is 7 mL, he m icrow ave radia ion pow er is 260 W , radia ion ime is 40 min , he yield of naph hyl e hyl e her exceed 71% . U sing his me hod ins ead of he original me hods, he reac ion ime can be shor ed( from 6h o 40 min) and he yield be increased( f rom 60% o 7 1%) . Key words:naph hyl e hyl e her ; m icrow ave radia ion ; reac ion condi ion ; syn hesis , 60 % , [ 7~ 9] , , , K F/ A l O , 2 3 , ( 70% ) , , , ( , , ) , , , , , , , , [ 1~ 3] : 1 ; ;