a-Ni(OH)2纳米线形成机理的研究.pdfVIP

（7） 纳米科学与技术 a-Ni(OH)2 纳米线形成机理研究 王浩然,邓意达,胡文彬* （上海交通大学金属基复合材料国家重点实验室 上海 200240） 摘 要：选用NiSO ，NiCl ，Ni(NO ) , NaOH 等原材料，采用水热法在 120℃制备a-Ni(OH) 纳米线，利 4 2 3 2 2 用X射线衍射 （XRD ），傅立叶变换红外光谱 （FTIR ），扫描电镜 （SEM ），透射电镜（TEM ），x 射线能谱 仪 （EDS）等技术对材料结构、形貌和成分进行了表征。研究表明：低的NaOH 浓度与高纯的SO42- 溶剂环 境是形成a-Ni(OH)2 纳米晶种的关键因素。低的NaOH 浓度与高纯的SO42- 溶液体系对Ni(OH)2 结构单元的 双重作用促进a-Ni(OH)2 纳米晶沿(001)面长大，进而形成宽20 ～30nm,长约数微米的a-Ni(OH)2 纳米线。 关键词：纳米材料；a-Ni(OH)2 纳米线；水热法；形成机理； Growth mechanism of a-Ni(OH)2 nanowires WANG Haoran, DENG Yida, HU Wenbin (State Key Laboratory of Metal Matrix composites, Shanghai Jiao Tong University, Shanghai, 200240) Abstract: a -Ni(OH) nanowires were successfully synthesized by hydrothermal method only using NiSO NiCl ， 2 4, 2 Ni(NO ) and NaOH . The samples were characterized by means of X-ray diffraction (XRD), Fourier, Transform 3 2 infrared spectroscopy (FTIR), field-emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), high -resolution transmission electron microscopy (HRTEM) and energy dispersive analysis system of x-ray (EDS) . The study reveals that low amount of NaOH and pure SO42- environment is the key factor of synthesis a-Ni(OH)2 nano-wires .Low NaOH concentration and high purity of SO42-solution system promote a-Ni (OH) 2 nanocrystalline growing along the (001) face and form wide 20 ~ 30 nm, a few microns long a -Ni (OH) 2 nanowires. Key words: nano-materials; a -Ni(OH) nano-wires; hydrothermal; growth mechanism.