影响二氧化硅溶胶粒径及粒度分布因素的研究.pdfVIP

第 16 卷第 2 期 粉末冶金材料科学与工程 2011 年 4 月 Vol.16 No.2 Materials Science and Engineering of Powder Metallurgy Apr. 2011 影响二氧化硅溶胶粒径及粒度分布因素的研究 何捍卫，赵世伟，贾守亚 ( 中南大学 粉末冶金国家重点实验室，长沙 410083) 摘 要：以氢氧化钾为催化剂，用硅粉溶解法制备硅溶胶，通过扫描电镜(SEM)、激光粒度分析(SL)、pH 值和粘 度测试对所得硅溶胶进行表征。研究反应温度、硅粉加入量、氢氧化钾加入量和反应时间对胶粒粒径、粒度分布 以及形貌的影响，并对粒径增长进行理论分析。结果表明：随着反应温度的升高，平均粒径先增大后减小，粒径 分散度先减小后增大；随着硅粉加入量的增加，平均粒径先增加后降低，粒径分散度先增大后减小；随着氢氧化 钾加入量的增加，平均粒径先增大后减小，粒径分散度变化不大；随着反应时间的延长，平均粒径逐渐增大，粒 径分散度逐渐增加，反应时间达到 10 h 时，胶粒发生团聚；胶粒形貌呈球形。 关键词：硅溶胶；粒径；粒度分布 中图分类号：TQ127.2 文献标识码：A 文章编号：1673-0224(2011)2-266-06 Study on factors of particle size and distribution of silica sol HE Han-wei, ZHAO Shi-wei, JIA Shou-ya (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: Using potassium hydroxide as catalyst ，silica sol was prepared through silicon dissolution method. The morphology, particle size and size distribution of colloidal particle were characterized by means of scanning electron microscope(SEM), laser size distribution analyzer(SL), pH and viscosity measurements. On this basis, effects of reaction temperature, dosage of silica powder, dosage of potassium hydroxide, reaction time on particle size, size distribution and morphology were investigated, and the theories of crystal growth were also explored. The results show that: with the increasing of reaction temperature, mean particle size firstly increases then decreases, particle size dispersity firstly decreases then increases; with the increasin