基于TGA的生物质热解特性和动力学研究.pdfVIP

基于TGA 的生物质热解特性及动力学研究 樊永胜，蔡忆昔，李小华，赵卫东 ，俞宁 (江苏大学 汽车与交通工程学院 江苏 镇江 212013) 摘要：为优化生物质热解工艺过程，研究了常见农林生物质的热解特性及其动力学参数的分布规律。利用热重分析仪对 4 种农林生物质的热解失重行为进行了试验研究，采用热解特性指数 P 对生物质的热解特性进行了综合评价，使用 Coats-Redfern 方法对生物质的热解过程进行了动力学分析研究。研究结果表明，生物质的热解反应可分为干燥预热、快 速失重和缓慢失重3 个阶段；各生物质在主热解区低温段所需的热解活化能要高于高温段；活化能和频率因子均随升温 速率增大而增大；采用n=2 级动力学模型能较好的表述整个主热解区的反应过程；采用 15K/min 的升温速率和500℃的 热解终温可提高热解反应速率，降低能耗。 关键词：生物质；热重分析；热解特性；动力学；能耗 Study on Biomass Pyrolysis Characteristics and Kinetics Based on TGA Fan Yongsheng ，Cai Yixi ，Li Xiaohua ，Zhao Weidong ，Yu Ning (School of Automotive and Traffic Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China) Abstract: In order to realize the optimization of pyrolysis process, the pyrolysis characteristics and kinetics of common agriculture and forestry biomass were studied. The thermogravimetric experiment was carried out on TGA, in which, four kinds of biomass were chosen as experiment materials. The pyrolysis characteristics index P was adopted to conduct a comprehensive evaluation of biomass pyrolysis characteristics. The method of Coats-Redfern was used to analyse pyrolysis kinetics of biomass pyrolysis. The results of research show that the thermal decomposition process of biomass can be divided into three stages, including drying and preheating, fast pyrolysis and slow decomposition of residue. The activation energy of thermal decomposition reaction of biomass during the low temperature stage is higher than that of the high temperature stage. The values of the activation energy and pre-exponential factor are increasing with the increase of heating rate. The thermal decomposition of biomass in the main pyrolysis zone can be effectively described by the kinetic model n=2. The heating rate of 15K/min and the temperature of 500℃ can improve the rea