CCFL铝酸盐荧光粉MgF2包膜.pdfVIP

O18 CCFL 铝酸盐荧光粉的 MgF2 包膜 陈蓉，董岩 （东南大学材料科学与工程学院，江苏 南京，211189 ） 摘要： CCFL用铝酸盐蓝色荧光粉在制灯以及工作过程中存在各种劣化现象，导致CCFL使用寿 命下降。本文采用非均相成核法在该荧光粉表面包覆MgF ，并研究了陈化pH值、包覆比例、HF 2 滴加速度等参数对MgF 膜层形貌的影响以及包膜后荧光粉热稳定性能。研究结果表明，陈化pH 2 值对MgF 包覆膜层的均匀性、致密度有显著影响，当pH 值为4左右时，包覆颗粒的均匀性和致 2 密度均最优。在此陈化pH值下，包覆量改变对MgF 包覆层的均匀性和致密度也有影响，当包覆 2 量为5%，MgF 颗粒将荧光粉完全致密包覆，且膜层厚度均匀。HF滴速缓慢、陈化pH值=4 、包 2 覆量=5% 时包覆膜层最为均匀致密，TEM结果表明膜层厚度约为100nm。此时包膜荧光粉的抗热 劣化性能亦最佳，经600℃，1h的热劣化后，包膜荧光粉的发光亮度较未包膜荧光粉提高11%。 关键词：CCFL ；荧光粉；表面包覆；MgF2 Research of Coating CCFL Aluminate Blue Phosphor with MgF2 Chen Rong，Dong Yan （Department of Materials Science and Engineering, Southeast University, Nanjing 211189, China ） Abstract ：CCFL aluminate blue phosphor exhibits degradations during the CCFL fabrication process and continuous operation, which leads deterioration of the performance of the CCFL. CCFL aluminate blue phosphor was coated with MgF2 according to the heterogeneous nucleation method, and various parameters were emphatically analyzed, we achieved a uniform compact film by controlling the aging pH value 、coating ratio、HF dropping speed 、temperature. The results showed that, the aging pH value is the key factor, only when aging pH=4, the surface of phosphors were covered with uniform MgF particles; coating ratio is another key factor, a uniform and 2 compact coating was obtained on the surface of the phosphor particles when