氨基硅油微乳液改性水性聚氨酯的合成和性能_宋海香.pdfVIP

2006 25 3 CHEMICAL INDUSTRY AND ENGINEERING PROGRESS ·319 · 1,3 1 2 2 2 , (AEAPS) 8.18% 0.92% TQ 323.8 TQ 264.17 A 2006)031905 Synthesis and properties of waterborne polyurethane modified with amino siloxane microemulsion 1,3 1 2 2 2 SONG Haixiang LUO Yunjun LIN Hongsheng LUO Jutao QU Shaomin 1 2 ( School of Materials Science and Engineering Beijing Institute of Technology, Beijing 100081 Zhejiang Transfar 3 Co., Ltd,Hangzhou 311215 Department of Chemical Engineering, Anyang Institute of Technology, Anyang 455000) Abstract A waterborne polyurethane emulsion and a kind of waterborne polyurethane modified with aminoethylaminopropyltrimethoxysilane (AEAPS) were prepared. Their properties and their application as fabric coating were studied. The results showed that the modified waterborne polyurethane had good centrifugal stability when the mass ratio of amino silicone oil to polypropylene glycol was 8.18% and there was 0.92% silicon on the surface of films casted from the modified waterborne polyurethane. Its microphase separation, water resistance and thermal stability were better. Furthermore, the fabric coated with the modified waterborne polyurethane had good softness and smoothness. Key word waterborne polyurethane; amino siloxane microemulsion; modified