Fe-1at%25C合金纳米晶球磨制备和稳定性研究.pdfVIP

C32 Fe-1at%C 合金纳米晶球磨制备及稳定性研究6 张柯， 刘峰, 宫明明 （西北工业大学凝固技术国家重点实验室，陕西西安 710072） 摘要：Fe-C合金作为传统的结构材料被广泛应用于各领域；通过晶粒的细化甚至纳米化，Fe-C合金的性能可以得 到大幅提高。本文采用机械球磨方法制备了Fe-1at%C单相固溶体纳米晶粉体材料，通过扫描电镜及X射线衍射仪 分析了球磨时间对粉末形貌和尺寸，以及晶粒尺寸的影响，应用Scherrer公式得出了平均晶粒尺寸同球磨时间的 关系。结果表明在当前实验条件下，球磨10h时，即已得到Fe-C单相固溶体；球磨时间达到85h以上，合金粉末 形貌及尺寸趋于稳定，晶粒尺寸稳定在8nm左右。由于大量晶界以及微观应变的存在，获得的Fe-C 纳米晶具有自 发长大趋势，本文用差热分析手段研究了不同等温条件下Fe-C纳米晶的热稳定性，结合晶粒长大热力学和动力学 理论，求得晶界扩散激活能及稳定晶粒尺寸等参数，并分析讨论了Fe-C纳米晶的晶粒稳定机制。 关键词：Fe-C合金，纳米晶，稳定性，机械球磨 Preparation of Fe-1at.%C nanocrystalline by mechanical milling and its thermal stability study Zhang Ke, Liu Feng, Gong Mingming (State Key Laboratory of Solidification Processing, Northwestern Polytechnical University, Xi’an Shaanxi, 710072, P.R. China) Abstract: As an important structural material, Fe-C alloys have been widely used in many fields. The properties of Fe-C alloy materials can be largely improved by grain refinement or even achieving nanocrystalline in them. In the present paper, the particles of Fe-1at.%C alloy with the single phase solid solution nanocrystalline have been produced by mechanical milling. The influences of milling time on the morphologies of particles and the grain size have been investigated by using X-ray diffraction (XRD) and scanning electron micrograph (SEM) methods. Applying Scherrer formula, the average grain size, furthermore the grain size evolution with the milling time has been obtained. The results show that the single phase solid solution has already been achieved after 10 hours of milling. After 85h of milling, both the morphology of the particles and the grain size became stable. And the final grain size of about 8nm has been reached. The Fe-C nanocrystall