铬锆掺杂磷酸铝介孔材料低热固相合成及表征.pdfVIP

无机盐工业 第 42卷第 期 18 INORGAN IC CHEM ICALS INDUSTRY 2010年 月 * , , , (, 556011) : X N -; 2 ; , ( ZrC rA lPO) ( C rA lPO) , BET P O M e(M e= C r, Zr) , : ; ; ; ; : TQ133. 1 : A : 1006- 4 0( 2010) 0 - 0018- 05 Syn th esis and characterization of z ircon ium, chrom ium doped a lum inophosphate m esoporous - m aterials via solid state reaction at low tem perature Liu Shaoyou, TangW enhua, Jiang T ianzh,i W en Zhengkang (Schoo l of App lied Chem istry, K aili Univ ersity, K a ili 556011, Ch ina ) A bstrac t: A lum inium phosphate (A lPO ), chrom ium alum inophosphate ( C rA lPO) , and zircon ium chrom ium alum ino 4 phosphate ( ZrCrAlPO) m esoporous m aterialsw ere prepared d irectly by solid- state reaction rou te. Phase structures of those m aterialsw ere characterized by XRD, TEM, SEM, N - phys isorption, and FT- IR. Contents of doped elementsw ere deter 2 m ined by inductively couple p lasm a atom ic em ission spectrom etry ( ICP - AES). Changes of infrared spectra am ong ZrC rA lPO, C rA lPO, and A lPO were compared. Resu lts show ed that chrom ium and zirconium have been incorporated into the 4 fram ework of alum inophosphate (A lPO ). ZrC rA lPO and C rA lPO m esoporous m aterialsw ith high specific surface areaw ere 4 m ainly com posed ofw orm- like, amorphous, and sphericalm icrostructures. M eanwh ile, as the dop ing of Zr and C r, stretch ing vibration and bend