重有色金属冶炼中砷的脱除和回收.pdfVIP

2003年8月 中国有色金属学会第五届学术年会论文集 Aug·2003 重有色金属冶炼中砷的脱除与回收 魏昶，姜琪，罗天骄，黄孟阳 (昆明理工大学材料与冶金学院，云南昆明650093) 摘要：介绍了铜、锡、铅、锌重有色金属冶炼过程中砷的分布和脱除情况。铜冶炼的脱砷重点在铜 电解液的净化，主要采用电解法和溶剂萃取法，而铜冶炼过程中火法脱砷研究较少。锡精矿含砷 o5％--5 5％。一般在熔炼前进行焙烧脱砷，而冶炼过程中产生的高砷烟尘则采用电热回转窑焙烧法或湿 法脱砷。铅锌冶炼过程脱砷的研究集中在高铅砷转妒烟尘、铅阳极泥及次氧化锌的脱砷研究。 关键词：脱砷；重有色金属冶炼；高铅砷 ArsenicRemovaland in Metals Process RecoveryHeavy Smelting Wei Tian-jiao，HuangMeng-yang Chang,Jiang@Luo and ofMaterialsand ofScience (School Metallurgy，KunmingUniversity Technology，Kunming650093) in metalssuchas Absrtact：Thedistributionandremoval ofArsenicthe technology heavy copper，tin， leadandzinc areintroduced．Inthe is metallurgicalprocess，arsenic smeltingpmcesses copper inthe the andsolventextraction eliminated dominantly electrolytepurificationby electrolysis process． Therearefewresultsonthearsenicremovalwiththe for contentof smelting．The pyro—processcopper in tinconcentrateisabout forarsenicremovalthe arsenicthe 0．5％-5．5％．pre—treatment by masting fromthe isdealt is the dust with commonly．Howeverhigh—arsenic smeltingprocedure by processadopted the kilnor