聚合锆离子柱撑累托石矿物材料_管俊芳.pdfVIP

第28卷　第1期 　　　　　　　　 总第123期 Vol.28　No.1 Journal of Materials Science Engineering Feb .2010 :1673-2812(2010)01-0040-05 1 2 2 2 , , 　 , (1., 　430070;2., 　430074) 　　【　】　,(ZrOCl2 ·8H2O ) (), ,X D、FTI 、TG-DSC、SEM BET 001 。(d ) 3.0 ～3.2nm, 500°C 3.1nm; FTI Si-O [Si-O]-[H (O)-Zr];TG-DSC 418J/g,256J/g 134J/g;10 , ,。 【】　;;;FTI ;TG-DSC;SEM :TD985;X788　　　　:A Pillared RectoriteMineral Material with Zirconium Polycations 1 2 2 2 GU N Jun-fang , T NG Zhong-dao , LU Qi , HONG Han-lie (1.School of Resource Environmental Engineering;Wuhan University of Technology, Wuhan　430070, China; 2.China University of Geosciences, Wuhan　430074, China) 【bstract】　T he stable zirconium polycations are synthesized at room temperature with zirconium oxychlorination(ZrOCl2 ·8H2 O).TheZr-pillared rectorite is prepared using these pillaring-agents and rectorite that came from Zhong Xing, Hu Bei province.T he Zr-pillared rectorite was characterized by X D, FTI , TG- DSC, SEM and BET.The interlayer spacing of Zr-pillared rectorite is 3.0～3.2nm at room temperature, basal interlayer spacing is 3.1nm when it was calcinated at 500℃.The stable [Si-O]-[H (O)-Zr] chemical bond is formed between zirconium polycations and [SiO4] of rectorite, which was confirmed by FTI study.The absorptivity of Zr-pillared rectorite is 418J/g, 134J/g higher than rectorite (256J/g).The specific surface area of Zr-pillared rectorite is 10 times of rectorite.It is indicated that Zr-pillared rectorite mineral material possesses good temperature resistance and surface activity, indicating its potential applications. 【Ke