纳米二氧化钛薄膜的制备及特性研究_崔晓莉.pdfVIP

2002 10 　 　 　 　 215 ·1　7 · :　1001-227X(2002)05-0017-05 1 2 崔晓莉, 　江志裕 (1.复旦大学 材料科学系, 上海　200433;2.复旦大学 化学系, 上海　200433) :纳米二氧化钛薄膜由于具有优良的光催化活性而受到人们的重 。采用阳极 电沉积的方法在ITO 基体上制备二氧化钛纳米薄膜。研究了阳极电流密度和沉积 时间对纳米二氧化钛薄膜结构和附着力的影响,利用扫描电子显微技术和X 射线衍 射技术分析了二氧化钛薄膜的表面形貌和组织结构, 探讨了其光催化活性和亲水 性。结果表明, 纳米二氧化钛薄膜是由纳米级的颗粒组成, 颗粒间存在纳米级小孔, 该薄膜对于波长为400 ～700 nm 的可见光是透明的,具有优良的光催化活性和亲水 性。 :纳米薄膜;　二氧化钛;　阳极电沉积;　光催化活性;　亲水性 :TG178　　　　　　　:A Studies on the preparation and characteristics of titanium dioxide nano thin film CUI Xiao-li, JIANG Zhi-yu (1.De t.of Material Science, Fudan Univ., Shanghai 200433, China; 2.Chemistry De t., Fudan Univ., Shanghai 200433, China) Abstract:Titanium dioxide nano thin film has been em hasized for its excellent hotocatalytic activity.Herein, titanium dioxide nano thinfilm was re ared on ITO surface by anodic de osition.The effect of anodic current density and de osition time on structure and adhesion of titanium dioxide nano thin film obtainedwas investigat- ed.Surface mor hology and structure of the nano thin film were analyzed by means of SEM and XRD.Photo- catalytic activity and hydro hilicity thereof were studied as well.The results show that titanium dioxide nano thin film is com osed of nano articles with nano holes among them, which is trans arent to visible light with wave length of 400 to 700 nanometers, and has excellent hotocatalytic activity and hydro hilicity. Keywords:nano thin film;titanium dioxide;anodic de osition;hotocatalytic activity;hydro hilicity , 1　 、、 TiO 2 。9