蓖麻油水性聚氨酯树脂的合成与性能的研究.pdfVIP

24 3 Vol. 24 No. 3 2004 9 Chemistry and Industry of Forest Products ept. 2004 瞿金清, 陈焕钦 ( 华南理工大学 化工所, 广东 广州510640) QU J Q : ( C. O.) ( N 210) (T DI) ( DMPA) , C. O. / N 210 NCO/ OH NH/ NCO , ( FT- IR) C. O. , C. O./ N 210 11NCO/ OH 1. 61DMPA 5. 5% NH / NCO 0. 501 2 : ; :T Q630. 1; 565. 6 :A :0253- 24 17(2004) 03- 0078- 05 T UDIE ON YNTHE E AND PROPERT IE OF WAT ERBORNE POLYU RET HANE RE IN FROM CA T OR OIL QU Jinqing, CHEN Huanqin ( I nstit ute of Che mical Eng ineer ing , Sout h Chi na Un iv er si ty of T ech nology , Guangz hou 510640, China) Abstract: Waterborne polyurethane( WPU) was prepared by t he reaction of castor oil( C. O.) w ith polyether glycol ( N 210) , dimethoxypropionic acid( DM PA) and toluene diisocyanate( TDI) .The effects of mass ratio of castor oil, N 210, DMPA content, molar rat ios of NCO to OH and NH / NCO on the properties were investigated.The structure 2 of WPU was characterized by FTIR. It was found that mechanical propert ies and water resistance of WPU coating film were increased wit h addition of castor oil.At 11- 2 mass ratio of castor oil to N 210, 1. 6 molar rat io of NCO/ OH, 5. 5% DMPA content and 0. 50 molar ratio of NH / NCO, the castor oil waterborne polyurethane has excellent 2 filmforming property , high hardness, good resistances to water and petrol, and excellent adhesion to base materials. Key words: w aterborne polyurethane; castor oil , , ( VOC) ,