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聚丙烯酸复合材料的制备与调湿性能.pdf
24 2 Vol.24 No.2
2 0 1 0 4 CHINESE JOURNAL OF MATERIALS RESEARCH April 2 0 1 0
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TB332, TQ326 1005-3093(2010)02-0113-05
Synthesis and Humidity Controlling Behaviors of
Attapulgite/Polyacrylic Acid Composite
WANG Jihui∗∗ LI Yan ZHANG Ziyang
(School of Materials Science and Engineering, Tianjin University, Tianjin Key Laboratory of Composite
and Functional Materials, Tianjin 300072)
* Supported by Key Project of Tianjin Natural Science Foundation No.08JCZDJC18000 and Foundation of
Key Laboratory of Silicate Materials Science and Engineering (Wuhan University of Technology), Ministry
of Education, No.SYSJJ2004-05.
Manuscript received December 14, 2009; in revised form January 30, 2010.
** To whom correspondence should be addressed, Tel:(022 E–mail: jhwang@tju.edu.cn
ABSTRACT Attapulgite/polyacrylic acid composite was synthesized by using inverse suspend poly-
merization method, and the effects of attapulgite content, neutralization degree and crosslinker content on
surface morphology, structure and humidity controlling properties were investigated. The results show that
attapulgite/polyacrylic acid composite has a loose and porous surface. With the increase of attapulgite
content in composite, the humidity absorption and desorption rate increases firstly under the balance of
reduction of moisture absorption component and raising of surface porosity and then decreases. The
composite with higher neutralization degree has a higher absorption rate but has a lower deso
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