D1磁性微粒的表面改性及分散方式对硅油基磁性液体稳定性的影响.pdf

·· 232001 10.8nmFe O 2- 3 4 2- Fe3O4 Fe O Fe O 3 4 3 4 Fe3O4 TM271 A 1001-3830(2007)02-0033-04 Effects of Surface Modification and Dispersion Mode of Magnetic Particles on the Stability of Silicon-oil Based Magnetic Liquid ZHOU Hong-mei, ZHANG Mao-run, WU Feng-yi Department of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, China Abstract Silicon-oil-based magnetic liquid was prepared using globular Fe O particles with mean diameter of 3 4 about 10.8nm as matrix material, dispersing it in 2-methyl silicon oil after surface modification using variant anionic surfactant, and proper surfactant was determined according to its dispersion permeation. Surface modified magnetic particles were compositely coated by transition liquid and then dispersed in 2-methyl silicon oil to prepare silicon-oil-based magnetic liquid. The effects of surface modification of Fe3O4 particles on the stability of magnetic liquid was studied according to its permeation and saturation magnetization. Optimal proportion of every component was determined by orthogonal experiment, and the effect of dispersion mode on the stability was analyzed. The results indicate that for given size of Fe O particles, the stability of silicon-oil-based magnetic liquid is mainly determined by 3 4 usage of transition liquid Fe O particles and surfactant, and is also rela