微波法合成离子液体1_羟乙基_3_甲基咪唑四氟硼酸盐的研究.pdfVIP

38 4 Vol1 38 No14 2010 4 NEW CH EM ICAL MATERIALS # 37# 1--3- 1,2 1,2 1 1 郑举功 陈泉水 杨 婷 刘崇羽 ( 1. 东华理工大学材料科学与工程系, 抚州344000; 2. 东华理工大学核资源与环境教 部重点实验室, 南昌330013) 由1- 甲基咪唑和2- 氯乙醇通过微波法合成中间体氯化 1-羟乙基-3- 甲基咪唑, 考察了原料配比微波功率 加热方式和加热时间对中间体产率的影响中间体经阴离子交换得到 1-羟乙基-3- 甲基咪唑四氟硼酸盐离子液体通过 1 测定中间体的相对分子量分析其纯度, 目标产物的结构通过IRH-NMR 表征 离子液体( RTILs) , 微波, 中间体, 合成, 1-羟乙基-3- 甲基咪唑四氟硼酸盐 Study on the microwave-assisted synthesis of ionicliquid 1-hydroxyethyl-3-methyl imidazolium tetrafluoroborate 1, 2 1, 2 1 1 Zheng Jugong Chen Quanshui Yang T ing Liu Chongyu ( 1. Department of Material Science and Engineering, East China Institute of T echnology , Fuzhou 344000; 2. Key Laboratory of Nuclear Resources and Environment of M inistry of Education, East China Institute of T echnology, Nanchang 330013) Abstract The key intermediate, 1-buty-l 3-met hylimidazolium bromide w as synthesized effect ively from 1-met hylim- idazol and 2-chlorthanol under microwave irradiation. The influences of the molar ratio of raw material, microw ave pow er and heat ing styles and reaction t ime on the synt hetic reaction was also investigat ed. After an ionic exchange, the ionic liq- uid 1-hydroxyethyl-3-methyl imidazolium tetrafluoroborate were obtained. T he purity of the intermediat e w as determination by molecular w eight w ith volumetric precipitation method. T he structu