Chapter 16Introduction to Buffers.ppt

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * 1: Calculate the pH for the titration of HOAc by NaOH after 35 mL of 0.10 M NaOH has been added to 50 mL of 0.100 M HOAc. 2. If 45.0 mL of 0.250 M acetic acid, HC2H3O2, is titrated with 18.0 mL of 0.125 M sodium hydroxide, NaOH: What is the pH of the resulting solution? Ka for acetic acid is 1.8x10-5. What is the pH at the equivalence point? * Titration Curve of a Weak Base with a Strong Acid Tro, Chemistry: A Molecular Approach * Titration of a Polyprotic Acid if Ka1 Ka2, there will be two equivalence points in the titration the closer the Ka’s are to each other, the less distinguishable the equivalence points are titration of 25.0 mL of 0.100 M H2SO3 with 0.100 M NaOH pKa = 7.19 pKa = 1.85 Curve for the titration of a weak polyprotic acid. Titration of 40.00mL of 0.1000M H2SO3 with 0.1000M NaOH KEY POINTS 1. Weak acid has a higher pH since it is partially dissociated and less [H+] is present 2. pH rises rapidly in the beginning and slowly towards the equivalence point. 3. The pH at the equivalence point is not 7 (only applies to strong acid titration). * * * * * * * * * * * * * * * * * * * * * * * * * * Titration in an acid-base titration, a solution of unknown concentration (titrant) is slowly added to a solution of known concentration from a burette until the reaction is complete when the reaction is complete we have reached the endpoint of the titration an indicator may be added to determine the endpoint an indicator is a chemical that changes color when the pH changes when the moles of H3O+ = moles of OH?, the titration has reached its equivalence point * Titration * Acid-Base Indicators * Monitoring pH During a Titration the general method for monitoring the pH during the course of a titration is to measure the conductivity of the solution due to the [H3O+] using a probe that specifically measures just H3O+ the endpoint of the titration is reached at the equivalence poi