水热处理和尿素改性对三水铝石微观结构的影响.pdfVIP

24 1 Vol.24 No.1 2 0 1 0 2 CHINESE JOURNAL OF MATERIALS RESEARCH February 2 0 1 0 ∗ 1 1 2 1   2 1. 116028 2. , 110004 , , , 6 : 1 , 24 h ; 8 : 1 , Æ, , , , Æ Æ, , , , TB321 1005-3093(2010)01-0076-05 Influence of Hydrothermal Treatment and Urea Modification on the Microstructure of Gibbsite WANG Jing1∗∗ XU Bing1 FU Gaofeng2 SHI Jun1 YUAN Qi2 1.Liaoning Key Laboratory for Fabrication and Application of Super-fine Inorganic Powers, Dalian Jiaotong University, Dalian 116028 2. School of Materials and Metallurgy, Northeastern University, Shenyang 110004 * Supported by National Natural Science Foundation of China No the Project of Liaoning Educa- tion Department No.2008SD35, and the Science and Technology Program of Dalian City No.2008A13GX229. Manuscript received April 30, 2009; in revised form October 9, 2009. ** To whom correspondence should be addressed, Tel:(0411 E–mail:wangjing@djtu.edu.cn ABSTRACT Gibbsite was modified by using urea as modifying agent via a hydrothermal method. Effects of the amount of urea and hydrothermal times on the microstructures were investigated. The results show that the slice-like boehmite microstructure can be obtained at 140 for 24 h when the molar ratio of urea to gibbsite is less than 6 : 1, while the global ammonium aluminum carbonate hydroxide (AACH) microstructure can be prepared at 140 for 24 h when the molar ratio was more than 8 : 1. The formation of AACH depends on the hydrothermal times. Aluminum hydroxide turned from gibbsit