镁基储氢材料催化地研究进展.pdfVIP

134 材料导报A: 综述篇 2011 年5 月( 上) 第25 卷第5 期 * 1 1, 2 1 1 1, 2 应燕君 , 曾小勤 , 常建卫, 邹建新 , 丁文江 ( 1 , 200240; 2 , 200240) 过去十几年国内外对镁基储氢材料的催 剂研究表明, 使用催 剂能够有效改善材料的表面特性, 提 高材料的吸放氢动力学性能目前常用的催 剂体系有过渡族金属金属氧 物金属卤 物金属间 合物以及碳 素非金属通过比较发现, 不同种类的催 剂催 效果不同, 相应的催 机理也有所差异目前, 国外研究者已发现 几种催 剂共同催 的效果显著, 国内应加强金属间 合物和碳素材料催 剂以及不同催 剂共同作用方面的研 究 Research Progress of Catalysts for Mgbased Hydrogen Storage Materials 1 1, 2 1 1 1, 2 YING Yanjun , ZENG Xiaoqin , CHAN G Jianw ei , ZOU Jian in , DING Wenjiang ( 1 Shanghai Engineering Research Cent er of Magnesium Mat erials and Applicat ion, School of M aterials Science and Engineering , Shanghai Jiao T ong University , Shanghai 200240; 2 Key State Laboratory of Metal Matri Composit e, School of Materials Science and Engineering , Shanghai Jiao T ong University , Shanghai 200240) Abstract The cat aly sts of Mgbased hydrogen st orage materials are studied in the past decades. It shows that cataly sis is one of the critical factors in improving hydrogen sorption kinetics for metal hydride systems. All the cata ly sts are consisting of t ransition metals, metal o ides, metal halides, intermetallic compounds and nonmetal com pounds. The int ermetallic compounds and nonmetal compounds show great catalysis abilities in recent researchs. The catalytic effect and catalytic mechanism of all above cat alysts are review ed. Key words M gbased hydrogen storage materials, cataly sts, transition metal, metal o ides, metal halides, in termetallic compounds, nonmetal compounds 0 1 , ,