熔融盐焦油裂解实验的研究.pdfVIP

熔融盐焦油裂解实验研究* 王小波 1 2 3 赵增力 1 3** 谭中欣 1 3 李海滨 1 3 陈勇 1 3 (1. 中国科学院广州能源研究所固体废弃物能实验室 广州 510640) (2. 中国科学院研究生院 北京 100039) (3 中国科学院可再生能源与天然气水合物重点实验室 广州 510640 ) 摘 要：本文在小型实验炉内研究了甲苯热解特性，考察了熔融盐种类对甲苯热解产率、气体产物产率 及甲苯产率的影响。结果表明：熔融盐对焦油裂解有明显的催化作用。相同热解温度下甲苯热解率明显提 高。800℃热解时，与直接热解相比NK 盐和NN 盐甲苯裂解率分别提高27%和46% ；相同热解率下苯等 大分子产率明显减少。在 60% 甲苯裂解率时，与直接热解相比NK 盐和 NN 盐时苯产率分别减少 16%和 20% 。 关键词：生物质气化；焦油；熔融盐；热解 Experiment Study of Tar Pyrolysis in Eutectic salts WANG Xiaobo1,2,3, ZHAO Zengli1,3**, TAN Zhongxin1,3, LI Haibin1,3CHEN Yong1,3 (1 Chinese Academy of Science, GuangZhou Institute of Energy Conversion, Guangzhou 510640, China). (2 Graduate Institute of the Chinese Academy of Sciences, Beijin 100039, China) (3 Key Laboratory of Renewable Energy and Gas Hydrate, CAS, Guangzhou 510640, China) Abstract The pyrolysis experiments were carried out in a eutectic salts reactor. Catalytic effect of NN salt and NK salt on toluene pyrolysis rate, gas products generation rate and benzene generation rate were investigated. The result shows that: Eutectic salts have obvious effects of catalytic cracking on toluene. When pyrolysis with NK salt and NN salt toluene Pyrolysis rate are 27% and 46% higher respectively at the same temperature; when toluene pyrolysis rate is the same, the generation rate of benzene is clearly lower. When the pyrolysis rate is 60%, generation rate of benzene for NK salt and NN salt are 16% and 20% lower respectively than that of direct pyrolysis. Keywords biomass gasification; tar; eutectic salts; pyrolysis 焦油的存在对生物质气化及其利用都会产生不利影响。燃气焦油的存在首先降低了气 化炉效率。其次焦油在低温时凝结为液态，容易和水、焦炭等结合在一起，堵塞输气管道， 使气化设备运行发生困难。另外，凝结为细小液滴的焦油难以燃尽，在燃烧时容易产生碳 黑等颗粒，对燃气利用设备损害相当严重，这就大大降低了气化燃气的利