烟气硫酸与应用于沉钒工艺的研究.pdfVIP

·54· 伍珍秀，等：烟气硫酸应用于沉钒工艺研究 中国攀枝花 烟气硫酸应用于沉钒工艺研究 伍珍秀，孙朝晖，陈文龙，杜光超 （攀钢集团攀枝花钢铁研究院有限公司；钒钛资源综合利用国家重点实验室，四川 攀枝花 617000） 摘 要：模拟某钒厂沉钒方式分别用工业硫酸和烟气硫酸沉钒，以钒损和成本均最低的结果为依据进行探索实验。 选取其中钒损和成本低的一组试验，优化其工艺参数。试验结果表明，一步沉钒法的烟气硫酸沉钒钒损最小，成 本最低。其最优沉钒工艺参数：加沉钒剂后调节 pH 值为 2.2 ，99℃至沸腾沉钒 1h，每吨V O 钒损 3.06kg ，成本 2 3 763.18 元，远低于工业硫酸沉钒成本。技术应用于工业生产，沉钒上层液均值为 0.31g/L，完全满足生产要求。其 最终产品 V2O3 质量、粒度分布及堆比重均与工业硫酸沉钒水平相当。 关键词: 硫酸；烟气硫酸；沉钒；钒液 Technology research on vanadium precipitation with flu-gas sulfuric acid Zhenxiu Wu, Zhaohui Sun, Wenlong Chen, Guangchao Du (PanGang Group Research Institute Co., Ltd. State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization, Panzhihua, Sichuan, 617000, China) Abstract: The exploratory experiments of precipitating vanadium which simulated the process conditions in a vanadium plant with the indexes of vanadium loss and the cost were respectively tested with industrial sulfuric acid and flu-gas sulfuric acid in laboratory. The technology optimizations were studied by selecting the experimental group with the lowest vanadium loss and cost. The results indicate that the vanadium loss and cost are the lowest by one-step vanadium precipitation with flu-gas sulfuric acid, and the optimum processes are as follows: the pH is adjusted to 2.2 after adding the vanadium precipitation agent; the precipitation is proceeded 1 hour at 99℃ or 100 ℃. The vanadium loss and cost per 1000 kg V2O3 are respectively 3.06 kg and RMB 763.18 yuan by the optimum processes, which are much less than the processes with industrial sulfuric acid.Technology us