聚氧化乙烯挤出吹塑成型研究.pdfVIP

第 卷第 期 装 学 报 7 1 Vol.7 No.1 年 月 2015 1 Packaging Journal Jan. 2015 doi :10.3969/j .issn .1674-7100.2015.0 1.007 氧化乙烯挤出吹塑成型研究 郝喜海 阳家菊 文 舒 （湖南工业大学 包装与材料工程学院，湖南 株洲 412007 ） 摘 要：为能获得性能良好的PEO 水溶性薄膜，采用直接对PEO 挤出吹塑、先造粒再吹塑与改性后造 粒再吹塑等方法进行了研制，并针对改性剂（如增塑剂、稳定剂）的选择与改性剂配比量的选择进行了探 讨。选用甘油为增塑剂、乙二醇为稳定剂，并设置了PEO 与增塑剂、稳定剂的质量之比分别为18:1:1 8:1:1 的 组实验进行对比研究。随着增塑剂甘油添加质量分数的增加 的熔融温度降低；稳定 6:1:1 7:1:1.2 4 PEO 剂乙二醇的加入增加了PEO 的热稳定性，有效阻止了实验过程中的氧化现象。最后 定了吹塑与造粒的工 艺路线与工艺条件 找出了改性前后PEO 的最佳造粒温度与最佳吹塑温度，改性前造粒机机头位置至膜口 位置的最佳温度分别为120, 122, 125, 129 ℃；而改性剂用量不同，最佳吹塑温度也不同 且随改性剂用量的 增加而减小。改性前后吹塑出的制品均出现黏度小的现象 在以后的研究中需加入增加黏度的改性剂。 关键词： 薄膜；挤出吹塑；造粒；改性剂 PEO 中图分类号： 文献标志码： 文章编号： A 1674 7100 2015 01 0035 05 TQ323.5 - - - ’ Research on PEO s Extrusion-Blown Molding ， ， Hao Xihai Yang Jiaju Wen Shu （ ， ， ， ） School of Packaging and Materials Engineering Hunan University of Technology Zhuzhou Hunan 412007 China ： Abstract In order to produce the high performance PEO water-soluble film, the methods were researched by adopt- ing direct PEO extrusion-blown molding, blow molding after granulation, and modified, granulated and then blow-molding. The choice of modifier such as plasticizer and stabilizer and the proportion of different modifiers were discussed. Experimen- tal comparative study was conducted under the condition of the plasticizer being glycerol, stabilizer being ethylene glycol, the proportion of PEO and plasticizer, stabilizer being 18:1:1, 8:1:1, 6:1:1, 7:1:1.2 respectively. With the increase ofplasticizer content of glycerol, the melting temperature of PEO is decreased. Stabilizer ethylene glycol increased the thermal stability of PEO, which effectively prevented the oxidation in the process of experiment. The process routes and process conditions of blow molding and granulating were determined. The optimal granulation temperature and blow molding temperature before and after modified PEO were found. The optimal granulation temperatures before modified were 120, 122, 125 and 129℃in the