锌镍与镍磷双层膜的制备及抗蚀行为研究.pdfVIP

The 6th China Corrosion Conference Fabrication and Corrosion Behavior of Zn-Ni/ Ni-P Bilayer Films Zhou LIU, Mei YU, Jianhua LIU*, Songmei LI School of Materials Science and Engineering, Beihang University, Beijing, China, 100191 Email: liujh@buaa.edu.cn Abstract: The corrosion resistance of Zn-Ni/ Ni-P bilayer films deposited on 45# steel was studied. The morphology was observed by metalloscope. The corrosion behavior was studied by neutral salt spray test and immersion test. The results indicated that Zn-Ni and Ni-P were associative with structure of 3D nets, and microcrack was appeared on Zn-Ni, which significantly increased the binding force between two layers and impacted corrosion resistance of the bilayer films. After pitting corrosion initiated on the outer Ni-P layer, the inner Zn-Ni film began to corrode instead of the matrix. While Zn-Ni film deposited as the outer layer, it corroded as the anode, resulting corrosion products adhering on the inner Ni-P film, which delayed the initiation of pitting corrosion. Keywords: bilayer films; Zn-Ni; microcrack; Ni-P; corrosion resistance 锌镍和镍磷双层膜的制备及抗蚀行为研究 刘洲，于美，刘建华*，李松梅 北京航空航天大学，材料科学与工程学院，北京，100191 Email: liujh@buaa.edu.cn 摘 要：本文研究了45 号钢上电镀锌镍和化学镀镍磷双层膜的制备及耐腐蚀等性能。用金相显微镜 观察了镀层的形貌，采用中性盐雾实验和全浸实验研究了锌镍和镍磷双层膜的腐蚀情况。结果表明， 锌镍为底层镍磷为面层的双层膜呈三维网状结构，锌镍底层沿着晶界出现微裂纹，提高了膜层之间 的结合力，且影响到该双层膜的耐蚀性能。当镍磷做面层时，镍磷层发生点蚀后，锌镍底层开始代 替基体腐蚀。当锌镍做面层时，锌镍层为牺牲阳极，其腐蚀产物能附着在镍磷底层上，延缓镍磷层 的点蚀发生。 关键字：双层膜；锌镍镀层；微裂纹；镍磷镀层；耐蚀性 性比锌镀层高 7~10 倍，且氢脆敏感性很小[12] 。近年 1 引言 来，国内已将电镀Zn- Ni 合金应用于电缆桥架、煤矿