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JMEPEG (2013) 22:1194–1200 ASM International DOI: 10.1007/s11665-012-0378-x 1059-9495/$19.00 Microstructure and Properties of Cast B-Bearing High Speed Steel Hanguang Fu, Shengqiang Ma, Jianqiang Hou, Yongping Lei, and Jiandong Xing (Submitted February 8, 2012; in revised form August 27, 2012; published online September 18, 2012) Microstructure, mechanical properties, and wear resistance of B-bearing high-speed steel (HSS) roll material containing 0.90-1.00% C, 1.3-1.5% B, 0.8-1.5% W, 0.8-1.5% Mo, 4.6-5.0% Cr, 1.0-1.2% V, and 0.15-0.20% Ti were studied by means of the optical microscopy (OM), the scanning electron microscopy (SEM), x-ray diffraction (XRD), hardness, impact toughness, and pin-on-disk abrasion tests. The results showed that as-cast structure of B-bearing HSS consisted of a-Fe-, M (B,C) -, M (B C )-, and M (B,C)- 23 6 3 0.7 0.3 2 type borocarbides, a small quantity of retained austenite, and a small amount of TiC. The hardness and impact toughness values of as-cast B-bearing HSS reached 65-67 HRC and 80-85 kJ/cm2, respectively. There were many M (B,C) -precipitated phases in the matrix after tempering, and then, with increasing 23 6 temperature, the amount of precipitated phases increased considerably. Hardness of B-bearing HSS