羧基功能化石墨烯及其壳聚糖复合膜的制备与性能_宋秋生.pdfVIP

Vol. 24 No.3 288 Journal of Functional Polymers 2011 9 宋秋生, 李 萌, 张 恺, 许 顺, 钟振彪 ( 合肥工业大学化工学院, 合肥 230009) : 采用Hummers 法制备氧化石墨, 化学分散法制备羧 功能化石墨烯采用 FTIR XRD 对产物进行表征; 用静电自组装法将其与壳聚糖( CS) 复合制备复合膜, 对复合膜的荧光性能 及其修饰玻碳电极对葡萄糖的电催化氧化还原性能进行了研究结果表明: 制备的功能化石墨烯 含有羧 ; 壳聚糖石墨烯复合膜具有光致发光性能; 复合膜修饰玻碳电极对葡萄糖具有良好的电 催化氧化还原性能 : 壳聚糖; 石墨烯; 自组装; 电催化氧化还原; 复合膜 : TQ31 : A : 1008935 ( 2011) Preparation and Properties of Carboxyl Functionalized Graphene and Chitosan Composite Film SONG Qiusheng, LI M eng, ZHANG Kai, XU Shun, ZHON G Zhenbiao ( School of Chemical Engineering, Hefei University of T echnology , Hefei 230009, China) Abstract: Carboxyl functionalized graphene w as prepared by chemical dispersion and characterized by FT IR and XRD. Composite membrane of carboxyl functionalized grapheme w ith chitosan ( CS) w as prepared via electrostatic selfassembly. The fluorescence properties of the composite film and the electrocatalytic oxidationreduction properties of the composite membrane modified glassy carbon electrode for glucose w ere studied. Results show ed that the functionalized graphene w as successfully prepared and the composite membrane show ed good photoluminescence performance. Glassy carbon electrode modified w ith the com posite membrane show ed good performance of electrocatalytic oxidationreduction for glucose. Key words: chitosan; graphene; selfassembly; electrocatalytic oxidationreduction; composite film [ 1] , [ 23] [ 46] , , , [ ] , , , [ 810] [ 8] Wang ,