大长径比ZnS纳米线的制备、结构与生长机理.pdfVIP

Huaxue 物理化学学报(Wuli Xuebao) Acta 193 February Phy鼠-Chim．Sin．，2008，24(2)：193-196 【Article】 大长径比ZnS纳米线的制备、结构和生长机理 邓战强1 齐俊杰1 张跃1’z+ 廖庆亮t 黄运华， 曹佳伟1 摘要： 通过碳热辅助化学气相沉积法，以Au作为催化剂，在较低温度(800℃)制备了ZnS纳米线，其尺寸均匀， 表面光滑，直径约为40nln．具有很大的长径比，是典型的单晶纤锌矿六方结构．高分辨透射电镜和选区电子 solid)机理控制的． 关键词： ZnS；纳米线；制备；结构；生长机理 中图分类号：0643 andGrowthMechanismofZnSNanowireswith Synthesis，Structure 一’—‘—— Ratio HighAspect DENG Jun—JielZHANGYueLz‘LIAO QI Zhan—Qian91 Qing—Lian91 Yun—HualCAOJia．Weil HUANG and and (1Department Chemistry,UniversityofScienceTechnology 100083，P．兄China； ofMaterialsPhysics Beijing，Beijing 2State Metalsand and KeyLaboratoryforAdvancedMaterials,UniversityofScienceTechnologyBeijing,Beijing nanowires Abstract：ZnS were thedirectreactionofZnandS viacarbon． successfullysynthesizedthrough vapor assistedchemical methodwitllAu indicatedthatthesizeofZnS evaporationdeposition catalyst．11圮investigations 40nmwas theaxisofthewireandtllesurfaceswereslick． nanowireswithadiameterof uniform approximately along TheZnSnanowirewitha wurtzitestructurewasa structure．HRTEMandSEAD hexagonal tvpicalsinglecrystalline resultsdemonstratedthatthenanowire wasdifferen