铝管表面硅烷膜的制备及其耐蚀性能的研究.pdfVIP

铝管表面硅烷膜的制备及耐蚀性能研究 张春燕，满瑞林，平海银 （中南大学化学化工学院，湖南，长沙） 摘要：传统的铜管蒸发器由于成本等原因正逐步被铝管蒸发器代替。但是铝管表面的自然氧化膜 很薄，耐蚀性能差，一旦发生点蚀穿孔，会造成整台冰箱、冰柜报废。因此，使用前对铝管进行 防腐处理是必要的。本文采用浸渍法，在50℃下制备了乙烯基三甲氧基硅烷、有机缓蚀剂复合钝 化膜，通过正交试验得到最佳配方，硅烷15ml/L，有机缓蚀剂4g/L，乙醇15ml/L，PH=3.0。通过 析氢实验，电化学测试及铜加速盐雾试验对膜的耐蚀性进行测试。与空白相比，复合膜的存在明 显提高了铝管的耐蚀性，电化学测试结果表明复合膜自腐蚀电流降低了两个数量级，阻抗值提高 了近5倍，有效降低了铝管的腐蚀速率；SEM图显示复合膜较均匀致密，能对铝管起到较好的防 腐蚀作用。 关键词：铝管 硅烷 复合膜 缓蚀剂 耐蚀性 Preparation of Silane Films on the Surface of aluminum tube and Study on Corrosion Protection Chunyan Zhang ,Ruilin Man (School of Chemistry and Chemical Engineering, Central South University, Changsha ) Due to the cost of evaporator, aluminum tubes are edging out copper pipes. Corrosion resisting property of the blank aluminum tube is poor, and the moment aluminum tube was punched the refrigerator was out of use. So it is necessary to pretreatment it Vinyltrimethoxysilane-organic inhibitor composite film was prepared by impregnation at 50°C, the optimum technology, which were 15mL/L silane, 4g/Lorganic inhibitor was obtained, 15mL/L alcohol, PH=3.0, was obtained by orthogonal test. Corrosion resistance of aluminum tube surface were studied by collecting hydrogen experiment, copper accelerated salt spray test and electrochemical methods , and results showed that the silane films significantly increased the corrosion resistance of aluminum tubes. Tafel curves and electrochemical impedance spectroscopy indicate, compared with the blank the corrosion current density of composite film reduced Tafel curves and electrochemical impedance spectroscopy indicate, compared with the blank the corrosion current density of composite film reduced. Scanning electron microscope(SEM) observation show the co