富锂层状结构正极材料的新制备方法.pdfVIP

Journal of Power Sources 230 (2013) 76 e80 Contents lists available at SciVerse ScienceDirect Journal of Power Sources journal homepage: www.elsevi /locate/jpowsour Short communication Li-rich layered composite Li[Li0.2Ni0.2Mn0.6 ]O2 synthesized by a novel approach as cathode material for lithium ion battery Jing Lin a, Daobin Mu a, *, Ying Jin b, Borong Wu a, Yunfeng Ma a, Feng Wu a a Beijing Key Laboratory of Environmental Science and Engineering, School of Chemical Engineering and Environment, Beijing Institute of Technology, Beijing 100081, China b National Center for Materials Service Safety, University of Science and Technology Beijing, Beijing 100083, China h i g h l i g h t s Li-rich layered composite Li[Li0.2Ni0.2Mn0.6 ]O2 is synthesized by a novel approach. Carbon felt is used to control the particles growth and simplify the preparation. The composite exhibits high reversible capacity and excellent cycling stability. First-principles calculation is performed to identify the crystalline structure. a r t i c l e i n f o a b s t r a c t Article history: Li-rich layered composite Li[Li0.2Ni0.2Mn0.6 ]O2 is prepared by a novel approach in which carbon felt acts Received 18 October 2012 as a carrier for synthesis reaction. The as-prepared material is characterized by SEM, ICP and XRD, its Received in revised form electrochemical performance is also examined with galvanostatic charge/discharge and CV measure- 26 November 2012 ments. It is showed that the facile process controls effectively the p