氰化物测定机理的研究_张冬亭.pdfVIP

2002 28 9 Sept ember 2002 Industrial Sa et y and Environmental Protect ion # 39 # 张冬亭 ( 054001 ) , EDTA ; Study on the mechanism of cyanide determination Zhang Dongt ing ( The Chemistry Dep t . of X ingtai Coll ege Xi ngtai, Hebei 054001) Abstract The mechanism to extract easily - released cyanide with the method o dihydroxy succinic acid- zinc nit rate and to extract tot al cyanogen by way o phosphori c acid- BDT A is studied. T he conditions or det ermining cyanide with the isonicid- pyrazolinone photometric method are approached. Keywords predist illation easily - released cyanide total cy anogen optical density , , , 2 : , ; , , , , , 2 , 2K [ Fe( CN) ] + 12H SO + 12H O= Fe ( SO ) + 3K SO + 3 6 2 4 2 2 4 3 2 4 1 6( NH ) SO + 12CO { 4 2 4 , Ni( CN) + 3H SO + 2H O= NiSO + 2NH HSO + 2CO { 2 2 4 2 4 4 4 , 1. 1 ( ) , : , pH= 4 KSCN+ 2HNO = KHSO + 2NO { + HCN { 3 4 , , (