催化裂解聚苯乙烯制备碳纳米管的研究.pdfVIP

Researchonthepreparationofcarbonnanotubesfromcatalyticdecompositionofpolystyrene／GongYaotingetal ·55 · ResearchonthePreparationofCarbonNanotubesfrom Catalytic DecompositionofPolystyrene GONG Yaoting，LIU Baochun，HOU Chao (CollegeofSciences，NanjingUniversityofTechnology，Nanjing210009) Abstract A largequantityofgood-qualitycarbonnanotubeswithabout5～4OnlTlindiameterarepreparedbycata— lyticdecompositionofpolystyreneinnitrogenatmosphereat600(2．Characterizationofcarbonnanotubesiscarriedout byscanningelectronmicroscopy，transmissionelectronmicroscopyandRamanspectroscopy．Theresultsshow thatthe carbonnanotubesarewellgraphitizedwithonlyalittleamorphouscarboncoveringoutsidethecarbonnanotubewalls． Thecatalyticdecompositionofpolystyreneisapromisinggreen chemicalmethodforeconomicallyproducing carbon nanotubes． Keywords carbonnanotubes，polystyrene，scanningelectronmicroscopy，transmissionelectronmicroscopy 催化裂解聚苯乙烯制备碳纳米管的研究 龚耀庭，刘宝春，侯 超 (南京工业大学理学院，南京 210009) 摘要 通过在 600℃氮气气氛中催化裂解聚苯乙烯，制备了大量管径为5~40nm的高质量的碳纳米管。利用 扫描电子显微镜、透射电子显微镜和拉曼光谱对所制备的碳纳米管进行了表征。研究表明，所制备的碳纳米管石墨化 程度高，在碳纳米管的管壁上仅有少量的无定形碳存在。催化裂解聚苯乙烯制备碳纳米管是一种有前途、低成本的绿 色化学方法。 关键词 碳纳米管 聚苯乙烯 扫描电子显微镜 透射电子显微镜 Sincecarbonnanotubeswerediscoveredinarcdischargeap— carbon nanotubesbyusing polymerascarbon sources~ ． paratusbyIOirna[，theyhavegeneratedsignificantresearchac— Thisisveryusefulinthedisposa1ofusedpolmy erbecauseit tivityinchemistry，physicsandmaterialsdueto theirunusual couldcovertheusedpolymerintohighvaluecarbonnanotubes． structure，extraordinarymechanicaland electronicproperties． Forexample，Kukovitskyandhisco-workersreportedtheCVD