QDB_04耐硫变换催化剂的应用.pdfVIP

A pr. 2007 45 2 # 52# Chem ical Fertilizer Design 2007 4 QDB- 04耐硫变换催化剂的应用 1 1 2 2 , , , ( 1. , 047507; 2. , 266317 : 介绍了合成氨装置扩产改造方案和变换工艺指标; 简述了对QDB - 04 耐硫变换催化剂进行 能对比动 力学计算和工业侧线实验的情况; 从工艺流程催化剂装填催化剂升温硫化等方面论述了 QDB- 04 耐硫变换催 化剂的工业应用情况结果表明, 在不增加反应器和催化剂装填量的情况下, QDB - 04 耐硫变换催化剂变换活 较高, 变换炉出口 CO 指标至少可降低 0. 5% , 每年可产生经济效益约 1 6 80 万元 : QDB- 04 耐硫变换催化剂; 能对比; 动力学计算; 工业侧线实验; 工业应用 : TQ 426. 4 : B : 1004 - 890 1( 2007 02- 0052- 04 Application of QDB- 04 AntiOsulfur Shift Catalyst GU O JianOm in, D ING M ingOgong, L IU J ie, W ANG LuOyuan ( 1. T ianj i Coa l Chem ica l Engineering G roup C omp any L td. , Lu cheng Shanx i 047507 C hina; 2. Qingdao L ianx in Chem istry C omp any L td. , J iao hou Q ingdao 266317 Ch ina) Abstract: T h e product ion expans ion reform ation sch em e and sh ift process index es w ere introdu ced for the amm on ia synthesis p lant; au th or de- scribed the prop erty comparison, dynam ics calcu lation for theQ DB - 04 ant iOsu lfu r sh ift cataly st and th e s ituat ion of indus trial sideOlin e test; the industrial app lication s ituation of the QD B- 04 ant iOsu lfur sh ift catalys t w as d iscussed from aspects of process f low, cataly st f illing, cataly st heatOsulfurat ion etc. . It ind icates th at under the casew ithout add ing reactor and cataly st f illing quan tity, the sh if t activity of QD B- 04 an tiOsu lfur sh ift cataly st is h igher, the CO conten t index at the ou tlet of sh ift ing furnace can be reduced at least by 0. 5% , and the benefit 16. 8 @ 106 Y u an RM B can be ga ined annually. Keyw ords: QD B-