不同形状的金纳米粒子的表面增强拉曼光谱.pdfVIP

15 2 Vol1 15 No1 2 2003 7 CHINESE JOURNAL OF LIGHT SCATTERING July1 2003 : 10042 5929(2003)03 XXX * 胡建强, 张 勇, 任 斌, 韩国彬, 杨志林, 田中群 ( , , 361005, zqtian@xmu. edu. cn) : 5141 5nm , (SERS) , ( 600nm) ( 600nm) , , , SERS : ; ;; :O657137 : A Surface2enhanced Raman Spectroscopic Study of Gold Nanoparticles with Different Shapes HU Jian2qiang, ZHANG Yong, REN Bin, HAN Guo2bin, YANG Zhi2lin, TIAN Zhong2qun ( Chemistry Depa rt ment , Stat e Key La b f or P hysi ca l Chemistry of Sol id Surf aces, Xia men Un iv . , Xiamen 361005, Ch ina ) Abstract: In this communication, we obtained for the first time the SERS spectra of gold at the laser excitation of 514. 5 nm by fabricating the ordered array of gold nanoparticles with special shapes, e. g. , sphere, tadpole, andpearl2chain. Self2assemble method of these gold nanoparticlesisbriefly intro2 duced. In general, the enhancement of gold by the laser excitation of short wavelength ( 600 nm) is much less than that of longer wavelength ( 600 nm) becuase that the coupling between conduction electrons and interband electronic transitions by using 514. 5 nm depresses the quality of the surface plasmon resonance of gold metals considerably. Our observation reveals that the SERSof self2assembly gold nanoparticles with special shape can be rather high even using the green light excitation, which is mainly due to the lightning2rod effect. Key words: SERS; Gold nanoparticle; Special shape; Lightning rod effect. ( SERS), SERS, :, SER [1- 3]